{"id":10192,"date":"2026-11-13T11:08:15","date_gmt":"2026-11-13T02:08:15","guid":{"rendered":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/?p=10192"},"modified":"2026-11-14T21:34:57","modified_gmt":"2026-11-14T12:34:57","slug":"%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a","status":"publish","type":"post","link":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/","title":{"rendered":"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c"},"content":{"rendered":"\n<p class=\"wp-block-paragraph\">\u4f7f\u7528\u30d7\u30ed\u30b0\u30e9\u30e0\u30fb\u30e9\u30a4\u30d6\u30e9\u30ea\uff082026\u5e7411\u670812\u65e5\u73fe\u5728\uff09\uff08ChatGPT\u306b\u983c\u3093\u3060\u3089\u3001\u6570\u56de\u306e\u3084\u308a\u53d6\u308a\u3067\u3055\u304f\u3063\u3068\u4f5c\u6210\u30fb\u6539\u826f\u3057\u3066\u304f\u308c\u307e\u3057\u305f\u3002\u9a5a\u304d\u3067\u3059\u3002Version 0.1.6\u3002\uff09:<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li><a href=\"https:\/\/crest-lab.github.io\/crest-docs\/\">CREST 3.0.1<\/a>\uff08\u914d\u5ea7\u63a2\u7d22\uff09<\/li>\n\n\n\n<li><a href=\"https:\/\/xtb-docs.readthedocs.io\/en\/latest\/#\">xtb 6.7.1<\/a>\uff08\u534a\u7d4c\u9a13\u7684\u91cf\u5b50\u5316\u5b66\u8a08\u7b97\uff09<\/li>\n\n\n\n<li><a href=\"https:\/\/www.faccts.de\/orca\/\">ORCA 6.1.1<\/a>\uff08\u91cf\u5b50\u5316\u5b66\u8a08\u7b97\uff09<\/li>\n\n\n\n<li>Python 3.12.11\uff08Web\u30a2\u30d7\u30ea\u306e\u30d0\u30c3\u30af\u30a8\u30f3\u30c9\u3001\u8a08\u7b97\u5165\u529b\u306e\u751f\u6210\u3001\u7d50\u679c\u89e3\u6790\u3002\u6a19\u6e96\u30e9\u30a4\u30d6\u30e9\u30ea\u3092\u4f7f\u7528\uff09<\/li>\n\n\n\n<li>SQLite\uff08\u30e6\u30fc\u30b6\u30fc\u60c5\u5831\u30fb\u30b8\u30e7\u30d6\u5c65\u6b74\u306e\u7ba1\u7406\u3002Python\u6a19\u6e96\u306e<code class=\"\" data-line=\"\">sqlite3<\/code>\u30e2\u30b8\u30e5\u30fc\u30eb\u304b\u3089\u5229\u7528\uff09<\/li>\n\n\n\n<li>JavaScript\/HTML Canvas API\uff08\u5206\u5b50\u69cb\u9020\u30fb\u30b9\u30da\u30af\u30c8\u30eb\u306e\u63cf\u753b\u3002\u5916\u90e8\u63cf\u753b\u30e9\u30a4\u30d6\u30e9\u30ea\u3092\u4f7f\u308f\u305a\u72ec\u81ea\u5b9f\u88c5\uff09<\/li>\n\n\n\n<li>Slurm 20.11.9\uff08\u8a08\u7b97\u30b8\u30e7\u30d6\u306e\u6295\u5165\u30fb\u72b6\u614b\u7ba1\u7406\uff09<\/li>\n\n\n\n<li>Apache HTTP Server\uff08Web\u30a2\u30d7\u30ea\u306e\u516c\u958b\u30fb\u30ea\u30d0\u30fc\u30b9\u30d7\u30ed\u30ad\u30b7\uff09<\/li>\n<\/ul>\n\n\n\n<p class=\"wp-block-paragraph\">\u5b66\u90e8\u30cd\u30c3\u30c8\u30ef\u30fc\u30af\u304b\u3089\u306a\u3089\u30a2\u30af\u30bb\u30b9\u3067\u304d\u307e\u3059\uff08<a href=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/memo\/workstation\/#ECDNMR\">URL\u306f\u5185\u90e8\u5c02\u7528\u30da\u30fc\u30b8\u306b<\/a>\uff09\u3002\u5b66\u751f\u3055\u3093\u306f\u7c21\u5358\u306a\u5206\u5b50\u3067\u904a\u3093\u3067\u307f\u3066\u304f\u3060\u3055\u3044\u3002<\/p>\n\n\n\n<h2 class=\"wp-block-heading\">\u4f7f\u3044\u65b9: \u9162\u9178\u30a8\u30c1\u30eb\u3092\u4f8b\u306b<\/h2>\n\n\n\n<h3 class=\"wp-block-heading\">Step 1. \u5206\u5b50\u69cb\u9020\u306e\u8aad\u307f\u8fbc\u307f<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\">\u5206\u5b50\u69cb\u9020\u30d5\u30a1\u30a4\u30eb\uff08XYZ, SDF, MOL, PDB, MOL2\uff09\u3092\u8aad\u307f\u8fbc\u307f\u307e\u3059\u3002\u3068\u308a\u3042\u3048\u305a\u8a66\u3059\u3060\u3051\u306a\u3089\u3001\u5de6\u4e0b\u306e\u300c\u30a8\u30bf\u30ce\u30fc\u30eb\u306e\u5165\u529b\u4f8b\u300d\u30dc\u30bf\u30f3\u3092\u62bc\u3059\u3068\u30a8\u30bf\u30ce\u30fc\u30eb\u5206\u5b50\u304c\u8868\u793a\u3055\u308c\u307e\u3059\u3002\u3053\u306e\u4f8b\u3067\u306f\u9162\u9178\u30a8\u30c1\u30eb\u5206\u5b50\u306eXYZ\u30d5\u30a1\u30a4\u30eb\u3092\u8aad\u307f\u8fbc\u307f\u307e\u3057\u305f\u30023\u6b21\u5143\u69cb\u9020\u306f\u3001Avogadro\u306a\u3069\u3067\u4f5c\u6210\u3059\u308b\u304b\u3001\u5316\u5408\u7269\u304cPubChem\u306b\u767b\u9332\u3055\u308c\u3066\u3044\u308c\u3070\u30013D conformer\u2192DOWNLOAD COORDINATES\u304b\u3089SDF\u5f62\u5f0f\u306e\u30d5\u30a1\u30a4\u30eb\u3092\u30c0\u30a6\u30f3\u30ed\u30fc\u30c9\u3057\u3066\u5229\u7528\u3067\u304d\u307e\u3059\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"766\" src=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.51.51-PM-1024x766.png\" alt=\"\" class=\"wp-image-10193\" style=\"width:523px;height:auto\" srcset=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.51.51-PM-1024x766.png 1024w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.51.51-PM-300x224.png 300w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.51.51-PM-768x574.png 768w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.51.51-PM-1536x1148.png 1536w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.51.51-PM-2048x1531.png 2048w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<h3 class=\"wp-block-heading\">Step 2. \u914d\u5ea7\u63a2\u7d22\u306e\u8a08\u7b97\u6761\u4ef6\u306e\u8a2d\u5b9a\u3068\u5165\u529b\u30d5\u30a1\u30a4\u30eb\u306e\u4f5c\u6210\u3001\u8a08\u7b97\u306e\u6295\u5165\u3001 \u914d\u5ea7\u63a2\u7d22\u7d50\u679c\u306e\u78ba\u8a8d<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\">\u8a08\u7b97\u30ec\u30d9\u30eb\u3001\u6eb6\u5a92\u30e2\u30c7\u30eb\u3001\u6eb6\u5a92\u3001\u6b8b\u3059\u30b3\u30f3\u30db\u30de\u30fc\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u95be\u5024\u306a\u3069\u3092\u8a2d\u5b9a\u3057\u305f\u5f8c\u3001\u300c\u5165\u529b\u30d5\u30a1\u30a4\u30eb\u3092\u4f5c\u6210\u300d\u30dc\u30bf\u30f3\u3092\u30af\u30ea\u30c3\u30af\u3057\u3066\u304f\u3060\u3055\u3044\u3002<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">\u6b21\u306b\u300c\u8a08\u7b97\u6761\u4ef6\u30fb\u8cc7\u6e90\u8a2d\u5b9a\u30fb\u5165\u529b\u30d5\u30a1\u30a4\u30eb\u3092\u78ba\u8a8d\u3057\u307e\u3057\u305f\u3002\u300d\u306b\u30c1\u30a7\u30c3\u30af\u3092\u5165\u308c\u3066\u304b\u3089\u3001\u300cSlurm\u3078\u6295\u5165\u300d\u30dc\u30bf\u30f3\u3092\u30af\u30ea\u30c3\u30af\u3057\u3066\u304f\u3060\u3055\u3044\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"398\" src=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.55.48-PM-1024x398.png\" alt=\"\" class=\"wp-image-10194\" style=\"width:551px;height:auto\" srcset=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.55.48-PM-1024x398.png 1024w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.55.48-PM-300x116.png 300w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.55.48-PM-768x298.png 768w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.55.48-PM-1536x596.png 1536w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-4.55.48-PM-2048x795.png 2048w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<p class=\"wp-block-paragraph\">\u30b8\u30e7\u30d6\u30fb\u30ed\u30b0\u7ba1\u7406\u30bb\u30af\u30b7\u30e7\u30f3\u3067\u3001\u300cSlurm\u5f85\u6a5f\u4e2d\u2192Slurm\u5b9f\u884c\u4e2d\u2192\u5b9f\u884c\u7d42\u4e86\u30fb\u7d50\u679c\u3092\u78ba\u8a8d\u300d\u3068\u306a\u308c\u3070\u914d\u5ea7\u63a2\u7d22\u304c\u7d42\u4e86\u3067\u3059\u3002<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">\u300c\u89e3\u6790\u3078\u8ffd\u52a0\u300d\u30dc\u30bf\u30f3\u3092\u30af\u30ea\u30c3\u30af\u3059\u308b\u3068\u3001\u4e0b\u90e8\u306e\u300cCREST\u914d\u5ea7\u3068\u30a8\u30cd\u30eb\u30ae\u30fc\u300d\u30bb\u30af\u30b7\u30e7\u30f3\u3067\u5404\u914d\u5ea7\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u3068\u69cb\u9020\u3092\u78ba\u8a8d\u3067\u304d\u307e\u3059\u3002\u4eca\u56de\u306f6\u7a2e\u985e\u306e\u30b3\u30f3\u30db\u30de\u30fc\u304c\u5f97\u3089\u308c\u307e\u3057\u305f\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"662\" src=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-5.04.00-PM-1024x662.png\" alt=\"\" class=\"wp-image-10197\" style=\"width:705px;height:auto\" srcset=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-5.04.00-PM-1024x662.png 1024w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-5.04.00-PM-300x194.png 300w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-5.04.00-PM-768x497.png 768w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-5.04.00-PM-1536x994.png 1536w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-5.04.00-PM-2048x1325.png 2048w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<h3 class=\"wp-block-heading\">Step 3. ORCA\u3067\u306e\u69cb\u9020\u6700\u9069\u5316\u3001\u632f\u52d5\u89e3\u6790<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\">\u30b8\u30e7\u30d6\u30fb\u30ed\u30b0\u7ba1\u7406\u30bb\u30af\u30b7\u30e7\u30f3\u306b\u623b\u3063\u3066\u3001\u300c\u5168\u914d\u5ea7\u3092\u6b21\u3078\u300d\u30dc\u30bf\u30f3\u3092\u30af\u30ea\u30c3\u30af\u3059\u308b\u3068\u30016\u500b\u306e\u914d\u5ea7\u5168\u3066\u3092\u6b21\u306eDFT\u6700\u9069\u5316\u3068\u632f\u52d5\u89e3\u6790\u3078\u6301\u3063\u3066\u3044\u3051\u307e\u3059\u3002\u5de6\u5074\u306e\u5ea7\u6a19\u306b\u8907\u6570\u306e\u69cb\u9020\u304c\u8aad\u307f\u8fbc\u307e\u308c\u3066\u3044\u308b\u3053\u3068\u3092\u78ba\u8a8d\u3057\u3066\u304f\u3060\u3055\u3044\u3002<br>\u8a08\u7b97\u30ec\u30d9\u30eb\u306f\u4ee5\u4e0b\u306e\u6761\u4ef6\u3092\u9078\u3073\u307e\u3057\u305f:<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li>\u69cb\u9020\u6700\u9069\u5316: B3LYP\/6-31+G(d,p)\u3001\u6c17\u76f8<\/li>\n\n\n\n<li>\u632f\u52d5\u89e3\u6790: B3LYP\/6-311+G(2d,p)\u3001\u30af\u30ed\u30ed\u30db\u30eb\u30e0\u6eb6\u5a92<\/li>\n<\/ul>\n\n\n\n<p class=\"wp-block-paragraph\">\uff08\u6ce8: ORCA\u306f\u8a08\u7b97\u3092\u9ad8\u901f\u5316\u3059\u308b\u305f\u3081\u3001\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u6c4e\u95a2\u6570\u306b\u5bfe\u3057\u3066\u30c7\u30d5\u30a9\u30eb\u30c8\u3067RIJCOSX\u8fd1\u4f3c\u3092\u4f7f\u7528\u3057\u307e\u3059\uff09\u3002\u3068\u308a\u3042\u3048\u305a\u904a\u3093\u3067\u307f\u308b\u306a\u3089\u3001B3LYP\/6-31G(d) \u3084B3LYP\/def2-SVP\u30ec\u30d9\u30eb\uff08\u6c17\u76f8\uff09\u3067\u8a66\u3057\u3066\u307f\u3066\u304f\u3060\u3055\u3044\u3002B3LYP\/6-31G(d) \u30ec\u30d9\u30eb\u3060\u3068\u3001\u5206\u5b50\u91cf400\u7a0b\u5ea6\u306e\u4f4e\u5206\u5b50\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u4e00\u70b9\u8a08\u7b97\u306b30\u301c50\u79d2\u307b\u3069\uff0818 CPU\u306e\u4e26\u5217\u8a08\u7b97\uff09\u304b\u304b\u308a\u307e\u3059\u30022014\u5e74\u306ePierens\u306e\u8ad6\u6587\u3067\u306f\u3001NMR\u4e88\u6e2c\u306e\u524d\u306e\u69cb\u9020\u6700\u9069\u5316\u3092B3LYP\/6-31+G(d,p), \u6c17\u76f8\u3067\u3001\u3055\u3089\u306b\u30b3\u30f3\u30db\u30de\u30fc\u6bd4\u3092\u8a08\u7b97\u3059\u308b\u305f\u3081\u306bB3LYP\/6-311++G(2d,p) + \u6eb6\u5a92\u30e2\u30c7\u30eb\u3067\u518d\u69cb\u9020\u6700\u9069\u5316\u3068\u632f\u52d5\u89e3\u6790\u3092\u884c\u3063\u3066\u3044\u307e\u3059\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"725\" src=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.40.46-AM-1024x725.png\" alt=\"\" class=\"wp-image-10201\" style=\"aspect-ratio:1.4124483182478489;width:470px;height:auto\" srcset=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.40.46-AM-1024x725.png 1024w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.40.46-AM-300x212.png 300w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.40.46-AM-768x544.png 768w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.40.46-AM-1536x1087.png 1536w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.40.46-AM-2048x1450.png 2048w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<p class=\"wp-block-paragraph\">\u300c\u6700\u9069\u5316\u5f8c\u306b\u632f\u52d5\u89e3\u6790\u30fb\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u8a08\u7b97\u3092\u884c\u3046\u300d\u306b\u30c1\u30a7\u30c3\u30af\u3092\u5165\u308c\u3066\u304b\u3089\u3001\u300c\u5165\u529b\u30d5\u30a1\u30a4\u30eb\u3092\u4f5c\u6210\u300d\u30dc\u30bf\u30f3\u3092\u30af\u30ea\u30c3\u30af\u3057\u3066\u3001\u300c\u8a08\u7b97\u6761\u4ef6\u30fb\u8cc7\u6e90\u8a2d\u5b9a\u30fb\u5165\u529b\u30d5\u30a1\u30a4\u30eb\u3092\u78ba\u8a8d\u3057\u307e\u3057\u305f\u3002\u300d\u306b\u30c1\u30a7\u30c3\u30af\u3092\u5165\u308c\u3066\u304b\u3089\u3001\u300cSlurm\u3078\u6295\u5165\u300d\u30dc\u30bf\u30f3\u3092\u30af\u30ea\u30c3\u30af\u3057\u3066\u304f\u3060\u3055\u3044\u3002<br>\u30b8\u30e7\u30d6\u306e\u7d42\u4e86\u3092\u78ba\u8a8d\u3057\u305f\u3089\u300c\u5168\u914d\u5ea7\u3092\u6b21\u3078\u300d\u30dc\u30bf\u30f3\u3092\u30af\u30ea\u30c3\u30af\u3057\u307e\u3059\u3002<\/p>\n\n\n\n<h3 class=\"wp-block-heading\">Step 4. ORCA\u3067\u306eECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c<\/h3>\n\n\n\n<figure class=\"wp-block-image aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"559\" src=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.46.42-AM-1024x559.png\" alt=\"\" class=\"wp-image-10202\" style=\"aspect-ratio:1.8318840579710145;width:445px;height:auto\" srcset=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.46.42-AM-1024x559.png 1024w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.46.42-AM-300x164.png 300w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.46.42-AM-768x419.png 768w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.46.42-AM-1536x838.png 1536w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-9.46.42-AM-2048x1117.png 2048w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<p class=\"wp-block-paragraph\">\u30fbTDA:  B3LYP\/6-311+G(2d,p)\u3001\u30af\u30ed\u30ed\u30db\u30eb\u30e0\u6eb6\u5a92<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">\u306b\u8a2d\u5b9a\u3057\u3066\u3001\u300c\u6700\u9069\u5316\u5f8c\u306e\u5ea7\u6a19\u3092\u5165\u529b\u3057\u3001\u53ce\u675f\u30fb\u865a\u632f\u52d5\u30fb\u91cd\u8907\u3092\u78ba\u8a8d\u3057\u307e\u3057\u305f\u3002\u300d\u306b\u30c1\u30a7\u30c3\u30af\u2192\u300c\u5165\u529b\u30d5\u30a1\u30a4\u30eb\u3092\u4f5c\u6210\u300d\u3092\u30af\u30ea\u30c3\u30af\u2192\u300c\u8a08\u7b97\u6761\u4ef6\u30fb\u8cc7\u6e90\u8a2d\u5b9a\u30fb\u5165\u529b\u30d5\u30a1\u30a4\u30eb\u3092\u78ba\u8a8d\u3057\u307e\u3057\u305f\u3002\u300d\u306b\u30c1\u30a7\u30c3\u30af\u2192\u300cSlurm\u3078\u6295\u5165\u300d\u3092\u30af\u30ea\u30c3\u30af\u3001\u3067\u8a08\u7b97\u304c\u958b\u59cb\u3055\u308c\u307e\u3059\u3002<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">\u8a08\u7b97\u304c\u7d42\u4e86\u3057\u305f\u3089\u3001\u300c\u89e3\u6790\u3078\u8ffd\u52a0\u300d\u3092\u30af\u30ea\u30c3\u30af\u3057\u3066\u3001\u300c\u30b9\u30da\u30af\u30c8\u30eb\u3092\u8868\u793a\u30fb\u5e73\u5747\u3092\u8a08\u7b97\u300d\u3067\u30b9\u30da\u30af\u30c8\u30eb\u304c\u8868\u793a\u3055\u308c\u307e\u3059\u3002\u9ed2\u3044\u592a\u7dda\u304c\u30dc\u30eb\u30c4\u30de\u30f3\u5e73\u5747\u3067\u3059\u3002\u9162\u9178\u30a8\u30c1\u30eb\u306f\u30a2\u30ad\u30e9\u30eb\u306a\u5206\u5b50\u306a\u306e\u3067\u3001\u30a8\u30ca\u30f3\u30c1\u30aa\u30e1\u30ea\u30c3\u30af\u306a\u30b3\u30f3\u30db\u30de\u30fc\u5bfe\u304c\u8a08\u7b97\u306b\u542b\u307e\u308c\u3066\u3044\u308c\u3070\u3001\u76f8\u6bba\u3055\u308c\u3066\u30bc\u30ed\u306b\u306a\u308b\u306f\u305a\u3067\u3059\u304c\u3001\u306a\u3063\u3066\u3044\u307e\u305b\u3093\u3067\u3057\u305f\u3002\u93e1\u50cf\u914d\u5ea7\u306e\u53d6\u308a\u3053\u307c\u3057\u3084\u91cd\u307f\u4ed8\u3051\u306a\u3069\u3092\u542b\u3081\u3001\u539f\u56e0\u306f\u73fe\u5728\u78ba\u8a8d\u4e2d\u3067\u3059\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"964\" src=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.16.47-AM-1024x964.png\" alt=\"\" class=\"wp-image-10204\" style=\"aspect-ratio:1.0622518225938609;width:642px;height:auto\" srcset=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.16.47-AM-1024x964.png 1024w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.16.47-AM-300x282.png 300w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.16.47-AM-768x723.png 768w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.16.47-AM-1536x1446.png 1536w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.16.47-AM-2048x1928.png 2048w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<h3 class=\"wp-block-heading\">Step 5. ORCA\u3067\u306eNMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\">Pierens (2014) \u3067\u4f7f\u308f\u308c\u3066\u3044\u305f\u8a08\u7b97\u30ec\u30d9\u30ebFBS07\uff08mPW1PW91\/6-311+G(2d,p)\u3001chloroform\u6eb6\u5a92\uff09\u3067NMR\u30b9\u30da\u30af\u30c8\u30eb\u3092\u4e88\u6e2c\u3057\u307e\u3059\u3002\u305f\u3060\u3057\u3001Pierens\u306e\u4fc2\u6570\u306fGaussian\u306eIEF-PCM\u6761\u4ef6\u3067\u5f97\u3089\u308c\u305f\u3082\u306e\u3067\u3059\u3002\u672c\u4f8b\u306eORCA\u8a08\u7b97\u306b\u306f<a href=\"https:\/\/www.faccts.de\/docs\/orca\/6.0\/manual\/contents\/detailed\/solvationmodels.html\">SMD\uff08The Solvation Model based on Density\uff09<\/a>\u3092\u4f7f\u7528\u3057\u3066\u3001Pierens\u306e\u4fc2\u6570\u3092\u79fb\u7528\u3057\u307e\u3057\u305f\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"708\" height=\"1024\" src=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.19.12-AM-708x1024.png\" alt=\"\" class=\"wp-image-10203\" style=\"width:527px;height:auto\" srcset=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.19.12-AM-708x1024.png 708w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.19.12-AM-207x300.png 207w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.19.12-AM-768x1111.png 768w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.19.12-AM-1061x1536.png 1061w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.19.12-AM-1415x2048.png 1415w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.19.12-AM.png 1570w\" sizes=\"auto, (max-width: 708px) 100vw, 708px\" \/><\/figure>\n\n\n\n<p class=\"wp-block-paragraph\">\u300c\u6700\u9069\u5316\u5f8c\u306e\u5ea7\u6a19\u3092\u5165\u529b\u3057\u3001\u53ce\u675f\u30fb\u865a\u632f\u52d5\u30fb\u91cd\u8907\u3092\u78ba\u8a8d\u3057\u307e\u3057\u305f\u3002\u300d\u306b\u30c1\u30a7\u30c3\u30af\u2192\u300c\u5165\u529b\u30d5\u30a1\u30a4\u30eb\u3092\u4f5c\u6210\u300d\u3092\u30af\u30ea\u30c3\u30af\u2192\u5165\u529b\u78ba\u8a8d\u306e\u30c1\u30a7\u30c3\u30af \u2192\u300cSlurm\u3078\u6295\u5165\u300d\u3092\u30af\u30ea\u30c3\u30af\u2192\u8a08\u7b97\u7d42\u4e86\u5f8c\u306b\u300c\u89e3\u6790\u3078\u8ffd\u52a0\u300d\u3092\u30af\u30ea\u30c3\u30af\u3002<br>\u6b21\u306b\u3001\u30b9\u30da\u30af\u30c8\u30eb\u3092\u8868\u793a\u3059\u308b\u30aa\u30d7\u30b7\u30e7\u30f3\u3092\u6307\u5b9a\u3057\u307e\u3059\u3002NMR\u88dc\u6b63\u30d7\u30ea\u30bb\u30c3\u30c8\u306f\u300cFBS07\u300d\u3001\u88dc\u6b63\u4fc2\u6570\u306e\u6eb6\u5a92\u306f\u300cchloroform\u300d\u3092\u9078\u629e\u3057\u307e\u3059\u3002\u4e0b\u90e8\u306e\u7b49\u4fa1\u306a\u6838\u30b0\u30eb\u30fc\u30d7\u3067\u306f\u3001\u30e1\u30c1\u30ec\u30f3\u57fa\u3092\u6307\u5b9a\u3059\u308b\u300cCH2@C3: 7,8\u300d\u3068\u3044\u3046\u884c\u3092\u624b\u52d5\u3067\u8ffd\u52a0\u3057\u307e\u3059\u3002\u88dc\u6b63\u4fc2\u6570\u306fGaussian\uff0fIEF-PCM\u3067\u6c42\u3081\u3089\u308c\u305f\u6587\u732e\u5024\u3092\u4f7f\u7528\u3057\u3066\u3044\u307e\u3059\u3002\u4eca\u56de\u306f\u8a08\u7b97\u30d7\u30ed\u30b0\u30e9\u30e0\u30fb\u6eb6\u5a92\u30e2\u30c7\u30eb\u30fb\u69cb\u9020\u6761\u4ef6\u304c\u7570\u306a\u308b\u305f\u3081\u3001\u8ad6\u6587\u3068\u540c\u7b49\u306e\u7cbe\u5ea6\u3092\u4fdd\u8a3c\u3059\u308b\u3082\u306e\u3067\u306f\u3042\u308a\u307e\u305b\u3093\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"793\" src=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.47.01-AM-1024x793.png\" alt=\"\" class=\"wp-image-10205\" style=\"aspect-ratio:1.2913112325688307;width:567px;height:auto\" srcset=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.47.01-AM-1024x793.png 1024w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.47.01-AM-300x232.png 300w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.47.01-AM-768x594.png 768w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.47.01-AM-1536x1189.png 1536w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-10.47.01-AM-2048x1585.png 2048w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<p class=\"wp-block-paragraph\"><br>\u6700\u5f8c\u306b\u3001\u300c\u30b9\u30da\u30af\u30c8\u30eb\u3092\u8868\u793a\u30fb\u5e73\u5747\u3092\u8a08\u7b97\u300d\u30dc\u30bf\u30f3\u3092\u62bc\u3059\u3068\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u304c\u4e0b\u90e8\u306b\u8868\u793a\u3055\u308c\u307e\u3059\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"787\" src=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-11.09.27-AM-1024x787.png\" alt=\"\" class=\"wp-image-10208\" style=\"aspect-ratio:1.3011477687992177;width:686px;height:auto\" srcset=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-11.09.27-AM-1024x787.png 1024w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-11.09.27-AM-300x231.png 300w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-11.09.27-AM-768x590.png 768w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-11.09.27-AM-1536x1181.png 1536w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-13-at-11.09.27-AM-2048x1575.png 2048w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<h4 class=\"wp-block-heading\">NMR\u4e88\u6e2c\u7d50\u679c\uff08in CHCl3; \u6587\u732e\u5024\u306fCDCl<sub>3<\/sub>\u4e2d\u306eresidual solvent peak\u306e\u5024\uff09<\/h4>\n\n\n\n<p class=\"wp-block-paragraph\">\u9162\u9178\u30a8\u30c1\u30eb\u306eNMR\u4e88\u6e2c\u5024\u3092\u3001Fulmer\u3089\u304c\u5831\u544a\u3057\u305fCDCl\u2083\u4e2d\u306e\u5316\u5b66\u30b7\u30d5\u30c8\u3068\u6bd4\u8f03\u3057\u307e\u3057\u305f\u3002\u8a08\u7b97\u3067\u306f\u30af\u30ed\u30ed\u30db\u30eb\u30e0\u306e\u9023\u7d9a\u6eb6\u5a92\u30e2\u30c7\u30eb\u3092\u4f7f\u7528\u3057\u3066\u3044\u307e\u3059\u3002<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Gregory R. Fulmer,&nbsp;Alexander J. M. Miller,&nbsp;Nathaniel H. Sherden,&nbsp;Hugo E. Gottlieb,&nbsp;Abraham Nudelman,&nbsp;Brian M. Stoltz,&nbsp;John E. Bercaw,&nbsp;Karen I. Goldberg; NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist.&nbsp;<em><em>Organometallics<\/em><\/em>&nbsp;10 May 2010; 29 (9): 2176\u20132179.&nbsp;<a href=\"https:\/\/doi.org\/10.1021\/om100106e\" target=\"_blank\" rel=\"noopener\">https:\/\/doi.org\/10.1021\/om100106e<\/a><\/p>\n\n\n\n<figure class=\"wp-block-table is-style-stripes normal-case-table has-custom-css wp-custom-css-6b4c7427\"><table class=\"has-fixed-layout\"><thead><tr><th><sup>1<\/sup>H<\/th><th>\u4e88\u6e2c\u5024 \u03b4<sub>H<\/sub> \/ ppm (J in Hz)<\/th><th>\u6587\u732e\u5024 \u03b4<sub>H<\/sub> \/ ppm (J in Hz)<\/th><th>ChemDraw 20.0\u4e88\u6e2c\u5024 \/ ppm (J in Hz)<\/th><\/tr><\/thead><tbody><tr><td>CH<sub>3<\/sub>CO<\/td><td>2.13<\/td><td>2.05<\/td><td>2.04<\/td><\/tr><tr><td>C<em>H<\/em><sub>2<\/sub>CH<sub>3<\/sub><\/td><td>3.99 (6.4)<\/td><td>4.12 (7)<\/td><td>4.12 (8)<\/td><\/tr><tr><td>CH<sub>2<\/sub>C<em>H<\/em><sub>3<\/sub><\/td><td>1.34 (6.4)<\/td><td>1.26 (7)<\/td><td>1.26 (8)<\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<figure class=\"wp-block-table is-style-stripes normal-case-table has-custom-css wp-custom-css-7cb5146e\"><table class=\"has-fixed-layout\"><thead><tr><th><sup>13<\/sup>C<\/th><th>\u4e88\u6e2c\u5024 \/ ppm<\/th><th>\u6587\u732e\u5024 \/ ppm<\/th><th>ChemDraw 20.0\u4e88\u6e2c\u5024 \/ ppm<\/th><\/tr><\/thead><tbody><tr><td><em>C<\/em>H<sub>3<\/sub>CO<\/td><td>20.76<\/td><td>21.04<\/td><td>20.7<\/td><\/tr><tr><td>CO<\/td><td>173.64<\/td><td>171.36<\/td><td>170.2<\/td><\/tr><tr><td>CH<sub>2<\/sub><\/td><td>61.64<\/td><td>60.49<\/td><td>61.0<\/td><\/tr><tr><td>CH<sub>3<\/sub><\/td><td>14.17<\/td><td>14.19<\/td><td>14.1<\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<h2 class=\"wp-block-heading\">\u5929\u7136\u7269\u306e<sup>1<\/sup>H\u304a\u3088\u3073<sup>13<\/sup>C NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c: Mexicanin I<\/h2>\n\n\n\n<p class=\"wp-block-paragraph\">Mexicanin I\u306f\u3001\u30ad\u30af\u79d1\u306e\u591a\u5e74\u8349<em>Helenium mexicanum<\/em>\u304b\u3089\u5358\u96e2\u3055\u308c\u308bPseudoguaiaine\u9aa8\u683c\u3092\u6709\u3059\u308b\u30bb\u30b9\u30ad\u30c6\u30eb\u30da\u30f3\u30e9\u30af\u30c8\u30f3\u3067\u3059\u3002\u5206\u5b50\u5f0f\u306fC<sub>15<\/sub>H<sub>18<\/sub>O<sub>4<\/sub>\u3001\u5206\u5b50\u91cf262.30 g\/mol\u3002Dra\u010d\u00ednsk\u00fd <em>et al.<\/em> (2012) \u3068Pierens (2014) \u3067\u3001\u691c\u8a3c\u306b\u4f7f\u308f\u308c\u3066\u3044\u305f\u306e\u3067\u3001\u8a08\u7b97\u3057\u3066\u307f\u307e\u3057\u305f\u3002<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">\u8a08\u7b97\u6761\u4ef6: <\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li>\u521d\u671f\u69cb\u9020: PubChem\u304b\u30893D conformer\u3092SDF\u5f62\u5f0f\u3067\u30c0\u30a6\u30f3\u30ed\u30fc\u30c9\uff08<a href=\"https:\/\/pubchem.ncbi.nlm.nih.gov\/compound\/Mexicanin-I\">https:\/\/pubchem.ncbi.nlm.nih.gov\/compound\/Mexicanin-I<\/a>\uff09<\/li>\n\n\n\n<li>\u914d\u5ea7\u63a2\u7d22: GFN2-xTB\/ALPB(CHCl3)\u3001-ewin 2.5 (kcal\/mol)<\/li>\n\n\n\n<li>\u69cb\u9020\u6700\u9069\u5316\u3001RIJCOSX-B3LYP\/6-31+G(d,p)\uff08\u6c17\u76f8\uff09; \u518d\u69cb\u9020\u6700\u9069\u5316+\u632f\u52d5\u89e3\u6790\u3001SMD(chloroform)\/RIJCOSX-B3LYP\/6-311+G(2d,p); NMR\u4e88\u6e2c\u3001\u6c17\u76f8\u3067\u306e\u6700\u9069\u5316\u69cb\u9020\u3092\u4f7f\u3063\u3066SMD(chloroform)\/RIJCOSX-mPW1PW91\/\/6-311+G(2d,p)\u3002<\/li>\n<\/ul>\n\n\n\n<p class=\"wp-block-paragraph\">CREST\u3067\u306e\u914d\u5ea7\u63a2\u7d22\u3067\u6700\u5b89\u5b9a\u304b\u30892.5 kcal\/mol\u4ee5\u5185\u306b\u5f97\u3089\u308c\u305f\u306e\u306f6\u4f4d\u306eOH\u57fa\u306e\u6c34\u7d20\u539f\u5b50\u306e\u5411\u304d\u304c\u7570\u306a\u308b3\u7a2e\u985e\u306e\u30b3\u30f3\u30db\u30de\u30fc\u3060\u3051\u3067\u3057\u305f\u3002\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u5dee\u306f0.0000, 0.7211, 1.9205 kcal\/mol\u3001\u5b58\u5728\u6bd4\u306f74.894, 22.177, 2.929%\uff08298.15 K, 1 atm\uff09\u3002<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">\u8a08\u7b97\u6642\u9593\uff08DFT\u8a08\u7b97\u306b\u306f18CPU\u4f7f\u7528\uff09\u306f\u3001<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li>\u914d\u5ea7\u63a2\u7d22\u30016\u5206<\/li>\n\n\n\n<li>\u69cb\u9020\u6700\u9069\u5316\uff08\u6c17\u76f8\uff09\u3001\u54046\u301c9\u5206<\/li>\n\n\n\n<li>\u518d\u69cb\u9020\u6700\u9069\u5316 + \u632f\u52d5\u89e3\u6790\uff08CHCl<sub>3<\/sub>\uff09\u3001\u540440\u5206\u7a0b\u5ea6<\/li>\n\n\n\n<li>NMR\u4e88\u6e2c\u3001\u540421\u5206<\/li>\n<\/ul>\n\n\n\n<p class=\"wp-block-paragraph\">\u3067\u5408\u8a083\u6642\u9593\u534a\u7a0b\u5ea6\u3067\u3057\u305f\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"762\" height=\"822\" src=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/mexicanin-I.png\" alt=\"\" class=\"wp-image-10254\" style=\"aspect-ratio:0.9270263584641179;width:278px;height:auto\" srcset=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/mexicanin-I.png 762w, https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/mexicanin-I-278x300.png 278w\" sizes=\"auto, (max-width: 762px) 100vw, 762px\" \/><figcaption class=\"wp-element-caption\">Mexicanin I\u306e\u69cb\u9020<\/figcaption><\/figure>\n\n\n\n<figure class=\"wp-block-table normal-case-table is-style-stripes has-custom-css wp-custom-css-35147871\"><table class=\"has-fixed-layout\"><thead><tr><th><sup>1<\/sup>H<\/th><th class=\"has-text-align-right\" data-align=\"right\">\u4e88\u6e2c\u5024\u03b4<sub>H<\/sub> (SMD\/CHCl<sub>3<\/sub>) \/ ppm <\/th><th class=\"has-text-align-right\" data-align=\"right\">Exp. \u03b4<sub>H<\/sub> (in CDCl<sub>3<\/sub>) \/ ppm <\/th><th class=\"has-text-align-right\" data-align=\"right\">\u0394\u03b4 (\u4e88\u6e2c<br>\u2212 Exp.)<\/th><th class=\"has-text-align-right\" data-align=\"right\">ChemDraw 20.0 \u03b4<sub>H<\/sub> \/ ppm<\/th><th><sup>13<\/sup>C<\/th><th class=\"has-text-align-right\" data-align=\"right\">\u4e88\u6e2c\u5024\u03b4<sub>C<\/sub> (SMD\/CHCl<sub>3<\/sub>) \/ ppm <\/th><th class=\"has-text-align-right\" data-align=\"right\">Exp. \u03b4<sub>C<\/sub> (in CDCl<sub>3<\/sub>) \/ ppm <\/th><th class=\"has-text-align-right\" data-align=\"right\">\u0394\u03b4 (\u4e88\u6e2c<br>\u2212 Exp.)<\/th><th class=\"has-text-align-right\" data-align=\"right\">ChemDraw 20.0 \u03b4<sub>C<\/sub> \/ ppm<\/th><\/tr><\/thead><tbody><tr><td><strong>H-1<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">2.77<\/td><td class=\"has-text-align-right\" data-align=\"right\">2.68<\/td><td class=\"has-text-align-right\" data-align=\"right\">0.09<\/td><td class=\"has-text-align-right\" data-align=\"right\">2.00<\/td><td><strong>C-1<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">54.12<\/td><td class=\"has-text-align-right\" data-align=\"right\">52.87<\/td><td class=\"has-text-align-right\" data-align=\"right\">1.25<\/td><td class=\"has-text-align-right\" data-align=\"right\">53.3<\/td><\/tr><tr><td><strong>H-2<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">7.92<\/td><td class=\"has-text-align-right\" data-align=\"right\">7.67<\/td><td class=\"has-text-align-right\" data-align=\"right\">0.25<\/td><td class=\"has-text-align-right\" data-align=\"right\">6.57<\/td><td><strong>C-2<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">169.55<\/td><td class=\"has-text-align-right\" data-align=\"right\">162.49<\/td><td class=\"has-text-align-right\" data-align=\"right\">7.06<\/td><td class=\"has-text-align-right\" data-align=\"right\">162.0<\/td><\/tr><tr><td><strong>H-3<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">6.00<\/td><td class=\"has-text-align-right\" data-align=\"right\">6.15<\/td><td class=\"has-text-align-right\" data-align=\"right\">-0.15<\/td><td class=\"has-text-align-right\" data-align=\"right\">6.07<\/td><td><strong>C-3<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">128.05<\/td><td class=\"has-text-align-right\" data-align=\"right\">130.24<\/td><td class=\"has-text-align-right\" data-align=\"right\">-2.19<\/td><td class=\"has-text-align-right\" data-align=\"right\">129.6<\/td><\/tr><tr><td><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td><strong>C-4<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">214.78<\/td><td class=\"has-text-align-right\" data-align=\"right\">214.35<\/td><td class=\"has-text-align-right\" data-align=\"right\">0.43<\/td><td class=\"has-text-align-right\" data-align=\"right\">209.0<\/td><\/tr><tr><td><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td><strong>C-5<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">58.87<\/td><td class=\"has-text-align-right\" data-align=\"right\">56.20<\/td><td class=\"has-text-align-right\" data-align=\"right\">2.67<\/td><td class=\"has-text-align-right\" data-align=\"right\">57.9<\/td><\/tr><tr><td><strong>H-6<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">4.43<\/td><td class=\"has-text-align-right\" data-align=\"right\">4.54<\/td><td class=\"has-text-align-right\" data-align=\"right\">-0.11<\/td><td class=\"has-text-align-right\" data-align=\"right\">3.55<\/td><td><strong>C-6<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">67.11<\/td><td class=\"has-text-align-right\" data-align=\"right\">65.76<\/td><td class=\"has-text-align-right\" data-align=\"right\">1.35<\/td><td class=\"has-text-align-right\" data-align=\"right\">72.4<\/td><\/tr><tr><td><strong>H-7<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">3.12<\/td><td class=\"has-text-align-right\" data-align=\"right\">3.11<\/td><td class=\"has-text-align-right\" data-align=\"right\">0.01<\/td><td class=\"has-text-align-right\" data-align=\"right\">2.57<\/td><td><strong>C-7<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">53.21<\/td><td class=\"has-text-align-right\" data-align=\"right\">52.73<\/td><td class=\"has-text-align-right\" data-align=\"right\">0.48<\/td><td class=\"has-text-align-right\" data-align=\"right\">49.2<\/td><\/tr><tr><td><strong>H-8<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">4.75<\/td><td class=\"has-text-align-right\" data-align=\"right\">4.81<\/td><td class=\"has-text-align-right\" data-align=\"right\">-0.06<\/td><td class=\"has-text-align-right\" data-align=\"right\">4.50<\/td><td><strong>C-8<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">76.48<\/td><td class=\"has-text-align-right\" data-align=\"right\">75.41<\/td><td class=\"has-text-align-right\" data-align=\"right\">1.07<\/td><td class=\"has-text-align-right\" data-align=\"right\">77.0<\/td><\/tr><tr><td><strong>H-9\u03b1<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">1.31<\/td><td class=\"has-text-align-right\" data-align=\"right\">1.39<\/td><td class=\"has-text-align-right\" data-align=\"right\">-0.08<\/td><td class=\"has-text-align-right\" data-align=\"right\">1.38<\/td><td><strong>C-9<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">43.16<\/td><td class=\"has-text-align-right\" data-align=\"right\">44.40<\/td><td class=\"has-text-align-right\" data-align=\"right\">-1.24<\/td><td class=\"has-text-align-right\" data-align=\"right\">42.5<\/td><\/tr><tr><td><strong>H-9\u03b2<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">2.34<\/td><td class=\"has-text-align-right\" data-align=\"right\">2.56<\/td><td class=\"has-text-align-right\" data-align=\"right\">-0.22<\/td><td class=\"has-text-align-right\" data-align=\"right\">1.48<\/td><td><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><\/tr><tr><td><strong>H-10<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">2.15<\/td><td class=\"has-text-align-right\" data-align=\"right\">2.22<\/td><td class=\"has-text-align-right\" data-align=\"right\">-0.07<\/td><td class=\"has-text-align-right\" data-align=\"right\">1.43<\/td><td><strong>C-10<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">29.36<\/td><td class=\"has-text-align-right\" data-align=\"right\">27.18<\/td><td class=\"has-text-align-right\" data-align=\"right\">2.18<\/td><td class=\"has-text-align-right\" data-align=\"right\">26.5<\/td><\/tr><tr><td><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td><strong>C-11<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">137.34<\/td><td class=\"has-text-align-right\" data-align=\"right\">134.63<\/td><td class=\"has-text-align-right\" data-align=\"right\">2.71<\/td><td class=\"has-text-align-right\" data-align=\"right\">136.8<\/td><\/tr><tr><td><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td><strong>C-12<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">168.96<\/td><td class=\"has-text-align-right\" data-align=\"right\">169.43<\/td><td class=\"has-text-align-right\" data-align=\"right\">-0.47<\/td><td class=\"has-text-align-right\" data-align=\"right\">170.0<\/td><\/tr><tr><td><strong>H-13<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">6.42<\/td><td class=\"has-text-align-right\" data-align=\"right\">6.41<\/td><td class=\"has-text-align-right\" data-align=\"right\">0.01<\/td><td class=\"has-text-align-right\" data-align=\"right\">6.33<\/td><td><strong>C-13<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">123.76<\/td><td class=\"has-text-align-right\" data-align=\"right\">122.84<\/td><td class=\"has-text-align-right\" data-align=\"right\">0.92<\/td><td class=\"has-text-align-right\" data-align=\"right\">122.5<\/td><\/tr><tr><td><strong>H-13&#8242;<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">5.72<\/td><td class=\"has-text-align-right\" data-align=\"right\">5.68<\/td><td class=\"has-text-align-right\" data-align=\"right\">0.04<\/td><td class=\"has-text-align-right\" data-align=\"right\">5.81<\/td><td><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><\/tr><tr><td><strong>H-14<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">1.18<\/td><td class=\"has-text-align-right\" data-align=\"right\">1.25<\/td><td class=\"has-text-align-right\" data-align=\"right\">-0.07<\/td><td class=\"has-text-align-right\" data-align=\"right\">0.88<\/td><td><strong>C-14<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">17.69<\/td><td class=\"has-text-align-right\" data-align=\"right\">19.75<\/td><td class=\"has-text-align-right\" data-align=\"right\">-2.06<\/td><td class=\"has-text-align-right\" data-align=\"right\">19.2<\/td><\/tr><tr><td><strong>H-15<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">1.16<\/td><td class=\"has-text-align-right\" data-align=\"right\">1.24<\/td><td class=\"has-text-align-right\" data-align=\"right\">-0.08<\/td><td class=\"has-text-align-right\" data-align=\"right\">1.24<\/td><td><strong>C-15<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">19.36<\/td><td class=\"has-text-align-right\" data-align=\"right\">20.28<\/td><td class=\"has-text-align-right\" data-align=\"right\">-0.92<\/td><td class=\"has-text-align-right\" data-align=\"right\">20.6<\/td><\/tr><\/tbody><tfoot><tr><td><strong>MAE<\/strong><\/td><td class=\"has-text-align-right\" data-align=\"right\">0.095<\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\">0.474<\/td><td><\/td><td class=\"has-text-align-right\" data-align=\"right\">1.800<\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\"><\/td><td class=\"has-text-align-right\" data-align=\"right\">1.793<\/td><\/tr><\/tfoot><\/table><figcaption class=\"wp-element-caption\">\u5b9f\u6e2c\u5024\u3068\u6838\u306e\u5e30\u5c5e\u306fDra\u010d\u00ednsk\u00fd <em>et al.<\/em>\uff082012\uff09\u306eSupporting Information\u3001Table S4\u306e\u5b9f\u6e2c\u5217C\uff08CDCl\u2083\uff09\u306b\u5f93\u3063\u305f\u3002\u0394\u03b4\u306f\u4e88\u6e2c\u5024\u2212\u5b9f\u6e2c\u5024\u3001\u5358\u4f4d\u306fppm\u3002<\/figcaption><\/figure>\n\n\n\n<p class=\"wp-block-paragraph\"><sup>1<\/sup>H\u306e\u5316\u5b66\u30b7\u30d5\u30c8\u306b\u3064\u3044\u3066\u306e\u6c7a\u5b9a\u4fc2\u6570<em>R<\/em><sup>2<\/sup> = 0.9978\u3001<strong>MAE = 0.095<\/strong>\u3001RMSD = 0.12\u3001<sup>13<\/sup>C\u306b\u3064\u3044\u3066\u306e\u6c7a\u5b9a\u4fc2\u6570<em>R<\/em><sup>2<\/sup> = 0.9987\u3001<strong>MAE = 1.80<\/strong>\u3001RMSD = 2.40\u3002<br>Pierens (2014) \u3067\u306e\u3001\u4e00\u756a\u8fd1\u3044\u8a08\u7b97\u6761\u4ef6\u306fFBS07 (B) \u3067\u3059\uff08Gaussian 09\u3067\u8a08\u7b97\uff09: 3\u3064\u306e\u30b3\u30f3\u30db\u30de\u30fc\u3001\u69cb\u9020\u6700\u9069\u5316\u306fB3LYP\/6-31+G(d,p)\uff08\u6c17\u76f8\uff09\u3001NMR\u4e88\u6e2c\u306fPCM(chloroform)\/B3LYP\/6-311+G(2d,p)\u3001\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u5dee\u3092\u6c42\u3081\u308b\u305f\u3081\u306e\u518d\u69cb\u9020\u6700\u9069\u5316+\u632f\u52d5\u89e3\u6790\u306fPCM(chloroform)\/B3LYP\/6-311+<strong>+<\/strong>G(2d,p)\u3002Pierens (2014) \u306eTable 3\u306b\u63b2\u8f09\u3055\u308c\u3066\u3044\u308b<strong>MAE = 0.091 for <sup>1<\/sup>H\u30011.935 for <sup>13<\/sup>C<\/strong>\u3067\u3057\u305f\u3002\u4eca\u56de\u306fRIJCOSX\u8fd1\u4f3c\u3092\u4f7f\u3063\u3066\u3044\u308b\u70b9\u3068\u518d\u69cb\u9020\u6700\u9069\u5316\/\u632f\u52d5\u89e3\u6790\u306e\u305f\u3081\u306e\u57fa\u5e95\u95a2\u6570\u304c\u9055\u3044\u307e\u3059\u304c\uff08H\u539f\u5b50\u306bdiffuse\u95a2\u6570\u3092\u8ffd\u52a0\u3057\u3066\u3044\u308b\uff09\u3001\u5316\u5b66\u30b7\u30d5\u30c8\u4e88\u6e2c\u306f\u304b\u306a\u308a\u826f\u304f\u518d\u73fe\u3067\u304d\u3066\u3044\u305d\u3046\u3067\u3059\u3002<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Mexicanin I\u306e<sup>1<\/sup>H\u3067\u306f\u3001MAE\u306f\u672c\u8a08\u7b970.095 ppm\u3001ChemDraw 20.0\u30670.474 ppm\u3067\u3057\u305f\u3002<sup>13<\/sup>C\u306eMAE\u306f\u305d\u308c\u305e\u308c1.800\u30011.793 ppm\u3067\u3001RMSD\u306f2.40\u30012.60 ppm\u3067\u3057\u305f\u3002\u8a08\u7b97\u6642\u9593\u304c3\u6642\u9593\u534a\u3068\u6570\u79d2\u3068\u3044\u3046\u3053\u3068\u3092\u8003\u3048\u308b\u3068\u3001ChemDraw\u3067\u306e<sup>13<\/sup>C\u5316\u5b66\u30b7\u30d5\u30c8\u4e88\u6e2c\u306e\u304a\u624b\u8efd\u3055\u3068\u512a\u79c0\u3055\u304c\u969b\u7acb\u3061\u307e\u3059\u306d\uff08\u4fa1\u683c\u306f\u9ad8\u3044\uff09\u3002<br>\u5929\u7136\u7269\u306e\u69cb\u9020\u6c7a\u5b9a\u306e\u8ad6\u6587\u3067\u306fDP4+\u3067\u3001\u3082\u3063\u3068\u3082\u3089\u3057\u3055\u304c\u8a55\u4fa1\u3055\u308c\u3066\u3044\u308b\u306e\u3092\u3088\u304f\u76ee\u306b\u3057\u307e\u3059\u3002DP4+\u306f\u3001\u5019\u88dc\u69cb\u9020\u306e\u8a08\u7b97NMR\u5316\u5b66\u30b7\u30d5\u30c8\u3068\u5b9f\u6e2c\u5024\u3068\u306e\u5dee\u3092\u3001\u8a08\u7b97\u30ec\u30d9\u30eb\u306b\u5bfe\u5fdc\u3059\u308b\u8aa4\u5dee\u5206\u5e03\u3067\u8a55\u4fa1\u3057\u3001\u5019\u88dc\u96c6\u5408\u5185\u3067\u306e\u76f8\u5bfe\u7684\u306a\u78ba\u7387\u3092\u63a8\u5b9a\u3059\u308b\u7d71\u8a08\u624b\u6cd5\u3067\u3059\u3002DP4+App\uff08<a href=\"https:\/\/pypi.org\/project\/dp4plus-app\/\">https:\/\/pypi.org\/project\/dp4plus-app\/<\/a> \uff09\u306f\u305d\u306e\u5b9f\u88c5\u306e\u4e00\u3064\u3067\u3059\u3002<\/p>\n\n\n\n<h2 class=\"wp-block-heading\">\u53c2\u8003\u6587\u732e<\/h2>\n\n\n\n<ul class=\"wp-block-list\">\n<li>Martin Dra\u010d\u00ednsk\u00fd,&nbsp;Milo\u0161 Bud\u011b\u0161\u00ednsk\u00fd,&nbsp;Beata War\u017cajtis,&nbsp;Urszula Rychlewska; Solution and Solid-State Effects on NMR Chemical Shifts in Sesquiterpene Lactones: NMR, X-ray, and Theoretical Methods.&nbsp;<em><em>J. Phys. Chem. A<\/em><\/em>&nbsp;2012; 116 (1): 680\u2013688.&nbsp;<a href=\"https:\/\/doi.org\/10.1021\/jp209408b\" target=\"_blank\" rel=\"noopener\">https:\/\/doi.org\/10.1021\/jp209408b<\/a><\/li>\n\n\n\n<li>Pierens GK. <sup>1<\/sup>H and <sup>13<\/sup>C NMR scaling factors for the calculation of chemical shifts in commonly used solvents using density functional theory. J Comput Chem. 2014;35(18):1388-94. doi: <a href=\"https:\/\/doi.org\/10.1002\/jcc.23638\">10.1002\/jcc.23638<\/a>.<\/li>\n<\/ul>\n\n\n\n<p class=\"wp-block-paragraph\">\uff08\u4e86\uff09<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4f7f\u7528\u30d7\u30ed\u30b0\u30e9\u30e0\u30fb\u30e9\u30a4\u30d6\u30e9\u30ea\uff082026\u5e7411\u670812\u65e5\u73fe\u5728\uff09\uff08C &#8230;<\/p>\n","protected":false},"author":1,"featured_media":10197,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_locale":"ja","_original_post":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/?p=10192","footnotes":""},"categories":[5],"tags":[],"class_list":["post-10192","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-5","ja"],"aioseo_notices":[],"aioseo_head":"\n\t\t<!-- All in One SEO 5.0.5.1 - aioseo.com -->\n\t<meta name=\"description\" content=\"\u4f7f\u7528\u30d7\u30ed\u30b0\u30e9\u30e0\u30fb\u30e9\u30a4\u30d6\u30e9\u30ea\uff082026\u5e7411\u670812\u65e5\u73fe\u5728\uff09\uff08ChatGPT\u306b\u983c\u3093\u3060\u3089\u3001\u6570\u56de\u306e\u3084\u308a\u53d6\u308a\u3067\u3055\u304f\u3063\u3068\u4f5c\" \/>\n\t<meta name=\"robots\" content=\"max-image-preview:large\" \/>\n\t<meta name=\"author\" content=\"RCY\"\/>\n\t<link rel=\"canonical\" href=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/\" \/>\n\t\t<meta name=\"generator\" content=\"All in One SEO (AIOSEO) 5.0.5.1\" \/>\n\t\t<meta property=\"og:locale\" content=\"ja_JP\" \/>\n\t\t<meta property=\"og:site_name\" content=\"\u9999\u5ddd\u5927\u5b66\u8fb2\u5b66\u90e8 \u30b1\u30df\u30ab\u30eb\u30d0\u30a4\u30aa\u30ed\u30b8\u30fc\u7814\u7a76\u5ba4 - Chemical Biology Laboratory, Faculty of Agriculture, Kagawa University\" \/>\n\t\t<meta property=\"og:type\" content=\"article\" \/>\n\t\t<meta property=\"og:title\" content=\"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c - \u9999\u5ddd\u5927\u5b66\u8fb2\u5b66\u90e8 \u30b1\u30df\u30ab\u30eb\u30d0\u30a4\u30aa\u30ed\u30b8\u30fc\u7814\u7a76\u5ba4\" \/>\n\t\t<meta property=\"og:description\" content=\"\u4f7f\u7528\u30d7\u30ed\u30b0\u30e9\u30e0\u30fb\u30e9\u30a4\u30d6\u30e9\u30ea\uff082026\u5e7411\u670812\u65e5\u73fe\u5728\uff09\uff08ChatGPT\u306b\u983c\u3093\u3060\u3089\u3001\u6570\u56de\u306e\u3084\u308a\u53d6\u308a\u3067\u3055\u304f\u3063\u3068\u4f5c\" \/>\n\t\t<meta property=\"og:url\" content=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/\" \/>\n\t\t<meta property=\"og:image\" content=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2021\/08\/Logo2021_2.png\" \/>\n\t\t<meta property=\"og:image:secure_url\" content=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2021\/08\/Logo2021_2.png\" \/>\n\t\t<meta property=\"article:published_time\" content=\"2026-11-13T02:08:15+00:00\" \/>\n\t\t<meta property=\"article:modified_time\" content=\"2026-11-14T12:34:57+00:00\" \/>\n\t\t<meta name=\"twitter:card\" content=\"summary\" \/>\n\t\t<meta name=\"twitter:site\" content=\"@cycloudone\" \/>\n\t\t<meta name=\"twitter:title\" content=\"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c - \u9999\u5ddd\u5927\u5b66\u8fb2\u5b66\u90e8 \u30b1\u30df\u30ab\u30eb\u30d0\u30a4\u30aa\u30ed\u30b8\u30fc\u7814\u7a76\u5ba4\" \/>\n\t\t<meta name=\"twitter:description\" content=\"\u4f7f\u7528\u30d7\u30ed\u30b0\u30e9\u30e0\u30fb\u30e9\u30a4\u30d6\u30e9\u30ea\uff082026\u5e7411\u670812\u65e5\u73fe\u5728\uff09\uff08ChatGPT\u306b\u983c\u3093\u3060\u3089\u3001\u6570\u56de\u306e\u3084\u308a\u53d6\u308a\u3067\u3055\u304f\u3063\u3068\u4f5c\" \/>\n\t\t<meta name=\"twitter:creator\" content=\"@cycloudone\" \/>\n\t\t<meta name=\"twitter:image\" content=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2021\/08\/Logo2021_2.png\" \/>\n\t\t<script type=\"application\/ld+json\" class=\"aioseo-schema\">\n\t\t\t{\"@context\":\"https:\\\/\\\/schema.org\",\"@graph\":[{\"@type\":\"BlogPosting\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#blogposting\",\"name\":\"\\u30d6\\u30e9\\u30a6\\u30b6\\u304b\\u3089\\u914d\\u5ea7\\u63a2\\u7d22\\u3001ECD\\u30b9\\u30da\\u30af\\u30c8\\u30eb\\u4e88\\u6e2c\\u3001NMR\\u30b9\\u30da\\u30af\\u30c8\\u30eb\\u4e88\\u6e2c - \\u9999\\u5ddd\\u5927\\u5b66\\u8fb2\\u5b66\\u90e8 \\u30b1\\u30df\\u30ab\\u30eb\\u30d0\\u30a4\\u30aa\\u30ed\\u30b8\\u30fc\\u7814\\u7a76\\u5ba4\",\"headline\":\"\\u30d6\\u30e9\\u30a6\\u30b6\\u304b\\u3089\\u914d\\u5ea7\\u63a2\\u7d22\\u3001ECD\\u30b9\\u30da\\u30af\\u30c8\\u30eb\\u4e88\\u6e2c\\u3001NMR\\u30b9\\u30da\\u30af\\u30c8\\u30eb\\u4e88\\u6e2c\",\"author\":{\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/author\\\/charlesy\\\/#author\"},\"publisher\":{\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/#organization\"},\"image\":{\"@type\":\"ImageObject\",\"url\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/wp\\\/wp-content\\\/uploads\\\/2026\\\/11\\\/Screenshot-2026-11-12-at-5.04.00-PM-scaled.png\",\"width\":2560,\"height\":1656},\"datePublished\":\"2026-11-13T11:08:15+09:00\",\"dateModified\":\"2026-11-14T21:34:57+09:00\",\"inLanguage\":\"ja\",\"mainEntityOfPage\":{\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#webpage\"},\"isPartOf\":{\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#webpage\"},\"articleSection\":\"\\u8a08\\u7b97\\u6a5f\"},{\"@type\":\"BreadcrumbList\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#breadcrumblist\",\"itemListElement\":[{\"@type\":\"ListItem\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/#listItem\",\"position\":1,\"name\":\"\\u30db\\u30fc\\u30e0\",\"item\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/\",\"nextItem\":{\"@type\":\"ListItem\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/category\\\/%e8%a8%88%e7%ae%97%e6%a9%9f\\\/#listItem\",\"name\":\"\\u8a08\\u7b97\\u6a5f\"}},{\"@type\":\"ListItem\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/category\\\/%e8%a8%88%e7%ae%97%e6%a9%9f\\\/#listItem\",\"position\":2,\"name\":\"\\u8a08\\u7b97\\u6a5f\",\"item\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/category\\\/%e8%a8%88%e7%ae%97%e6%a9%9f\\\/\",\"nextItem\":{\"@type\":\"ListItem\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#listItem\",\"name\":\"\\u30d6\\u30e9\\u30a6\\u30b6\\u304b\\u3089\\u914d\\u5ea7\\u63a2\\u7d22\\u3001ECD\\u30b9\\u30da\\u30af\\u30c8\\u30eb\\u4e88\\u6e2c\\u3001NMR\\u30b9\\u30da\\u30af\\u30c8\\u30eb\\u4e88\\u6e2c\"},\"previousItem\":{\"@type\":\"ListItem\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/#listItem\",\"name\":\"\\u30db\\u30fc\\u30e0\"}},{\"@type\":\"ListItem\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#listItem\",\"position\":3,\"name\":\"\\u30d6\\u30e9\\u30a6\\u30b6\\u304b\\u3089\\u914d\\u5ea7\\u63a2\\u7d22\\u3001ECD\\u30b9\\u30da\\u30af\\u30c8\\u30eb\\u4e88\\u6e2c\\u3001NMR\\u30b9\\u30da\\u30af\\u30c8\\u30eb\\u4e88\\u6e2c\",\"previousItem\":{\"@type\":\"ListItem\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/category\\\/%e8%a8%88%e7%ae%97%e6%a9%9f\\\/#listItem\",\"name\":\"\\u8a08\\u7b97\\u6a5f\"}}]},{\"@type\":\"Organization\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/#organization\",\"name\":\"\\u9999\\u5ddd\\u5927\\u5b66\\u8fb2\\u5b66\\u90e8 \\u30b1\\u30df\\u30ab\\u30eb\\u30d0\\u30a4\\u30aa\\u30ed\\u30b8\\u30fc\\u7814\\u7a76\\u5ba4\",\"description\":\"Chemical Biology Laboratory, Faculty of Agriculture, Kagawa University\",\"url\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/\",\"logo\":{\"@type\":\"ImageObject\",\"url\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/wp\\\/wp-content\\\/uploads\\\/2021\\\/08\\\/Logo2021_2.png\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#organizationLogo\",\"width\":150,\"height\":34},\"image\":{\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#organizationLogo\"},\"sameAs\":[\"https:\\\/\\\/twitter.com\\\/cycloudone\"]},{\"@type\":\"Person\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/author\\\/charlesy\\\/#author\",\"url\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/author\\\/charlesy\\\/\",\"name\":\"RCY\",\"image\":{\"@type\":\"ImageObject\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#authorImage\",\"url\":\"https:\\\/\\\/secure.gravatar.com\\\/avatar\\\/34d16afe1ee046192993e86c7a99cdd95b179fb2bba1c19ca9c61c4782cc8bcb?s=96&d=mm&r=g\",\"width\":96,\"height\":96,\"caption\":\"RCY\"}},{\"@type\":\"WebPage\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#webpage\",\"url\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/\",\"name\":\"\\u30d6\\u30e9\\u30a6\\u30b6\\u304b\\u3089\\u914d\\u5ea7\\u63a2\\u7d22\\u3001ECD\\u30b9\\u30da\\u30af\\u30c8\\u30eb\\u4e88\\u6e2c\\u3001NMR\\u30b9\\u30da\\u30af\\u30c8\\u30eb\\u4e88\\u6e2c - \\u9999\\u5ddd\\u5927\\u5b66\\u8fb2\\u5b66\\u90e8 \\u30b1\\u30df\\u30ab\\u30eb\\u30d0\\u30a4\\u30aa\\u30ed\\u30b8\\u30fc\\u7814\\u7a76\\u5ba4\",\"description\":\"\\u4f7f\\u7528\\u30d7\\u30ed\\u30b0\\u30e9\\u30e0\\u30fb\\u30e9\\u30a4\\u30d6\\u30e9\\u30ea\\uff082026\\u5e7411\\u670812\\u65e5\\u73fe\\u5728\\uff09\\uff08ChatGPT\\u306b\\u983c\\u3093\\u3060\\u3089\\u3001\\u6570\\u56de\\u306e\\u3084\\u308a\\u53d6\\u308a\\u3067\\u3055\\u304f\\u3063\\u3068\\u4f5c\",\"inLanguage\":\"ja\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/#website\"},\"breadcrumb\":{\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#breadcrumblist\"},\"author\":{\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/author\\\/charlesy\\\/#author\"},\"creator\":{\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/author\\\/charlesy\\\/#author\"},\"image\":{\"@type\":\"ImageObject\",\"url\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/wp\\\/wp-content\\\/uploads\\\/2026\\\/11\\\/Screenshot-2026-11-12-at-5.04.00-PM-scaled.png\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#mainImage\",\"width\":2560,\"height\":1656},\"primaryImageOfPage\":{\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/2026\\\/11\\\/13\\\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\\\/#mainImage\"},\"datePublished\":\"2026-11-13T11:08:15+09:00\",\"dateModified\":\"2026-11-14T21:34:57+09:00\"},{\"@type\":\"WebSite\",\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/#website\",\"url\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/\",\"name\":\"\\u9999\\u5ddd\\u5927\\u5b66\\u8fb2\\u5b66\\u90e8 \\u30b1\\u30df\\u30ab\\u30eb\\u30d0\\u30a4\\u30aa\\u30ed\\u30b8\\u30fc\\u7814\\u7a76\\u5ba4\",\"description\":\"Chemical Biology Laboratory, Faculty of Agriculture, Kagawa University\",\"inLanguage\":\"ja\",\"publisher\":{\"@id\":\"https:\\\/\\\/www.ag.kagawa-u.ac.jp\\\/charlesy\\\/#organization\"}}]}\n\t\t<\/script>\n\t\t<!-- All in One SEO -->\n\n","aioseo_head_json":{"title":"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c - \u9999\u5ddd\u5927\u5b66\u8fb2\u5b66\u90e8 \u30b1\u30df\u30ab\u30eb\u30d0\u30a4\u30aa\u30ed\u30b8\u30fc\u7814\u7a76\u5ba4","description":"\u4f7f\u7528\u30d7\u30ed\u30b0\u30e9\u30e0\u30fb\u30e9\u30a4\u30d6\u30e9\u30ea\uff082026\u5e7411\u670812\u65e5\u73fe\u5728\uff09\uff08ChatGPT\u306b\u983c\u3093\u3060\u3089\u3001\u6570\u56de\u306e\u3084\u308a\u53d6\u308a\u3067\u3055\u304f\u3063\u3068\u4f5c","canonical_url":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/","robots":"max-image-preview:large","keywords":"","webmasterTools":{"miscellaneous":""},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"BlogPosting","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#blogposting","name":"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c - \u9999\u5ddd\u5927\u5b66\u8fb2\u5b66\u90e8 \u30b1\u30df\u30ab\u30eb\u30d0\u30a4\u30aa\u30ed\u30b8\u30fc\u7814\u7a76\u5ba4","headline":"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c","author":{"@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/author\/charlesy\/#author"},"publisher":{"@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/#organization"},"image":{"@type":"ImageObject","url":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-5.04.00-PM-scaled.png","width":2560,"height":1656},"datePublished":"2026-11-13T11:08:15+09:00","dateModified":"2026-11-14T21:34:57+09:00","inLanguage":"ja","mainEntityOfPage":{"@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#webpage"},"isPartOf":{"@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#webpage"},"articleSection":"\u8a08\u7b97\u6a5f"},{"@type":"BreadcrumbList","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#breadcrumblist","itemListElement":[{"@type":"ListItem","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/#listItem","position":1,"name":"\u30db\u30fc\u30e0","item":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/","nextItem":{"@type":"ListItem","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/category\/%e8%a8%88%e7%ae%97%e6%a9%9f\/#listItem","name":"\u8a08\u7b97\u6a5f"}},{"@type":"ListItem","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/category\/%e8%a8%88%e7%ae%97%e6%a9%9f\/#listItem","position":2,"name":"\u8a08\u7b97\u6a5f","item":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/category\/%e8%a8%88%e7%ae%97%e6%a9%9f\/","nextItem":{"@type":"ListItem","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#listItem","name":"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c"},"previousItem":{"@type":"ListItem","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/#listItem","name":"\u30db\u30fc\u30e0"}},{"@type":"ListItem","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#listItem","position":3,"name":"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c","previousItem":{"@type":"ListItem","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/category\/%e8%a8%88%e7%ae%97%e6%a9%9f\/#listItem","name":"\u8a08\u7b97\u6a5f"}}]},{"@type":"Organization","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/#organization","name":"\u9999\u5ddd\u5927\u5b66\u8fb2\u5b66\u90e8 \u30b1\u30df\u30ab\u30eb\u30d0\u30a4\u30aa\u30ed\u30b8\u30fc\u7814\u7a76\u5ba4","description":"Chemical Biology Laboratory, Faculty of Agriculture, Kagawa University","url":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/","logo":{"@type":"ImageObject","url":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2021\/08\/Logo2021_2.png","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#organizationLogo","width":150,"height":34},"image":{"@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#organizationLogo"},"sameAs":["https:\/\/twitter.com\/cycloudone"]},{"@type":"Person","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/author\/charlesy\/#author","url":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/author\/charlesy\/","name":"RCY","image":{"@type":"ImageObject","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#authorImage","url":"https:\/\/secure.gravatar.com\/avatar\/34d16afe1ee046192993e86c7a99cdd95b179fb2bba1c19ca9c61c4782cc8bcb?s=96&d=mm&r=g","width":96,"height":96,"caption":"RCY"}},{"@type":"WebPage","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#webpage","url":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/","name":"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c - \u9999\u5ddd\u5927\u5b66\u8fb2\u5b66\u90e8 \u30b1\u30df\u30ab\u30eb\u30d0\u30a4\u30aa\u30ed\u30b8\u30fc\u7814\u7a76\u5ba4","description":"\u4f7f\u7528\u30d7\u30ed\u30b0\u30e9\u30e0\u30fb\u30e9\u30a4\u30d6\u30e9\u30ea\uff082026\u5e7411\u670812\u65e5\u73fe\u5728\uff09\uff08ChatGPT\u306b\u983c\u3093\u3060\u3089\u3001\u6570\u56de\u306e\u3084\u308a\u53d6\u308a\u3067\u3055\u304f\u3063\u3068\u4f5c","inLanguage":"ja","isPartOf":{"@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/#website"},"breadcrumb":{"@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#breadcrumblist"},"author":{"@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/author\/charlesy\/#author"},"creator":{"@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/author\/charlesy\/#author"},"image":{"@type":"ImageObject","url":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2026\/11\/Screenshot-2026-11-12-at-5.04.00-PM-scaled.png","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#mainImage","width":2560,"height":1656},"primaryImageOfPage":{"@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/#mainImage"},"datePublished":"2026-11-13T11:08:15+09:00","dateModified":"2026-11-14T21:34:57+09:00"},{"@type":"WebSite","@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/#website","url":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/","name":"\u9999\u5ddd\u5927\u5b66\u8fb2\u5b66\u90e8 \u30b1\u30df\u30ab\u30eb\u30d0\u30a4\u30aa\u30ed\u30b8\u30fc\u7814\u7a76\u5ba4","description":"Chemical Biology Laboratory, Faculty of Agriculture, Kagawa University","inLanguage":"ja","publisher":{"@id":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/#organization"}}]},"og:locale":"ja_JP","og:site_name":"\u9999\u5ddd\u5927\u5b66\u8fb2\u5b66\u90e8 \u30b1\u30df\u30ab\u30eb\u30d0\u30a4\u30aa\u30ed\u30b8\u30fc\u7814\u7a76\u5ba4 - Chemical Biology Laboratory, Faculty of Agriculture, Kagawa University","og:type":"article","og:title":"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c - \u9999\u5ddd\u5927\u5b66\u8fb2\u5b66\u90e8 \u30b1\u30df\u30ab\u30eb\u30d0\u30a4\u30aa\u30ed\u30b8\u30fc\u7814\u7a76\u5ba4","og:description":"\u4f7f\u7528\u30d7\u30ed\u30b0\u30e9\u30e0\u30fb\u30e9\u30a4\u30d6\u30e9\u30ea\uff082026\u5e7411\u670812\u65e5\u73fe\u5728\uff09\uff08ChatGPT\u306b\u983c\u3093\u3060\u3089\u3001\u6570\u56de\u306e\u3084\u308a\u53d6\u308a\u3067\u3055\u304f\u3063\u3068\u4f5c","og:url":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/","og:image":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2021\/08\/Logo2021_2.png","og:image:secure_url":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2021\/08\/Logo2021_2.png","article:published_time":"2026-11-13T02:08:15+00:00","article:modified_time":"2026-11-14T12:34:57+00:00","twitter:card":"summary","twitter:site":"@cycloudone","twitter:title":"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c - \u9999\u5ddd\u5927\u5b66\u8fb2\u5b66\u90e8 \u30b1\u30df\u30ab\u30eb\u30d0\u30a4\u30aa\u30ed\u30b8\u30fc\u7814\u7a76\u5ba4","twitter:description":"\u4f7f\u7528\u30d7\u30ed\u30b0\u30e9\u30e0\u30fb\u30e9\u30a4\u30d6\u30e9\u30ea\uff082026\u5e7411\u670812\u65e5\u73fe\u5728\uff09\uff08ChatGPT\u306b\u983c\u3093\u3060\u3089\u3001\u6570\u56de\u306e\u3084\u308a\u53d6\u308a\u3067\u3055\u304f\u3063\u3068\u4f5c","twitter:creator":"@cycloudone","twitter:image":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp\/wp-content\/uploads\/2021\/08\/Logo2021_2.png"},"aioseo_meta_data":{"post_id":"10192","title":null,"description":null,"keywords":null,"keyphrases":{"focus":{"keyphrase":"","score":0,"analysis":{"keyphraseInTitle":{"score":0,"maxScore":9,"error":1}}},"additional":[]},"primary_term":null,"canonical_url":null,"og_title":null,"og_description":null,"og_object_type":"default","og_image_type":"default","og_image_url":null,"og_image_width":null,"og_image_height":null,"og_image_custom_url":null,"og_image_custom_fields":null,"og_video":"","og_custom_url":null,"og_article_section":null,"og_article_tags":null,"twitter_use_og":false,"twitter_card":"default","twitter_image_type":"default","twitter_image_url":null,"twitter_image_custom_url":null,"twitter_image_custom_fields":null,"twitter_title":null,"twitter_description":null,"schema":{"blockGraphs":[],"customGraphs":[],"default":{"data":{"Article":[],"Course":[],"Dataset":[],"FAQPage":[],"Movie":[],"Person":[],"Product":[],"ProductReview":[],"Car":[],"Recipe":[],"Service":[],"SoftwareApplication":[],"WebPage":[]},"graphName":"BlogPosting","isEnabled":true},"graphs":[]},"schema_type":"default","schema_type_options":null,"pillar_content":false,"robots_default":true,"robots_noindex":false,"robots_noarchive":false,"robots_nosnippet":false,"robots_nofollow":false,"robots_noimageindex":false,"robots_noodp":false,"robots_notranslate":false,"robots_max_snippet":"-1","robots_max_videopreview":"-1","robots_max_imagepreview":"large","priority":null,"frequency":"default","local_seo":null,"breadcrumb_settings":null,"limit_modified_date":false,"ai":{"faqs":[],"keyPoints":[],"schemas":[],"titles":[],"descriptions":[],"socialPosts":{"email":{"subject":"","preview":"","content":""},"linkedin":[],"twitter":[],"facebook":[],"instagram":[]}},"created":"2026-11-12 08:00:04","updated":"2026-11-14 15:09:14","seo_analyzer_scan_date":null,"focus_keyword":null,"additional_keywords":null,"truseo_locale":null},"aioseo_breadcrumb":"<div class=\"aioseo-breadcrumbs\"><span class=\"aioseo-breadcrumb\">\n\t\t\t<a href=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/\" title=\"\u30db\u30fc\u30e0\">\u30db\u30fc\u30e0<\/a>\n\t\t<\/span><span class=\"aioseo-breadcrumb-separator\">\u00bb<\/span><span class=\"aioseo-breadcrumb\">\n\t\t\t<a href=\"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/category\/%e8%a8%88%e7%ae%97%e6%a9%9f\/\" title=\"\u8a08\u7b97\u6a5f\">\u8a08\u7b97\u6a5f<\/a>\n\t\t<\/span><span class=\"aioseo-breadcrumb-separator\">\u00bb<\/span><span class=\"aioseo-breadcrumb\">\n\t\t\t\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\n\t\t<\/span><\/div>","aioseo_breadcrumb_json":[{"label":"\u30db\u30fc\u30e0","link":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/"},{"label":"\u8a08\u7b97\u6a5f","link":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/category\/%e8%a8%88%e7%ae%97%e6%a9%9f\/"},{"label":"\u30d6\u30e9\u30a6\u30b6\u304b\u3089\u914d\u5ea7\u63a2\u7d22\u3001ECD\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c\u3001NMR\u30b9\u30da\u30af\u30c8\u30eb\u4e88\u6e2c","link":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/2026\/11\/13\/%e3%83%96%e3%83%a9%e3%82%a6%e3%82%b6%e3%81%8b%e3%82%89%e9%85%8d%e5%ba%a7%e6%8e%a2%e7%b4%a2%e3%80%81ecd%e3%82%b9%e3%83%9a%e3%82%af%e3%83%88%e3%83%ab%e4%ba%88%e6%b8%ac%e3%80%81nmr%e3%82%b9%e3%83%9a\/"}],"_links":{"self":[{"href":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp-json\/wp\/v2\/posts\/10192","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp-json\/wp\/v2\/comments?post=10192"}],"version-history":[{"count":46,"href":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp-json\/wp\/v2\/posts\/10192\/revisions"}],"predecessor-version":[{"id":10285,"href":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp-json\/wp\/v2\/posts\/10192\/revisions\/10285"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp-json\/wp\/v2\/media\/10197"}],"wp:attachment":[{"href":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp-json\/wp\/v2\/media?parent=10192"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp-json\/wp\/v2\/categories?post=10192"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.ag.kagawa-u.ac.jp\/charlesy\/wp-json\/wp\/v2\/tags?post=10192"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}